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Wide Range d33 Meter From APC International(7/28/2022)

PZT | Piezoelectric Materials from APC International

PIEZOELECTRIC MATERIALS (PZT) FROM APC INTERNATIONAL

APC International manufactures its custom piezoelectric elements from a selection of proprietary piezoelectric materials. Our lead zirconate titanate (PZT) materials are manufactured from some of the highest purity raw materials available on the market and have been developed and refined through years of extensive research and development.

APC has produced custom piezoelectric ceramics and PZT materials for over twenty-five years and we would like to be the one to manufacture the piezoelectric ceramics that meet your needs. However, if you would like to produce the piezoelectric ceramics on your own, APC offers many of its unprocessed PZT materials for direct sale to customers.

 

Materials from APC Overview
Choosing APC Material
APC Materials - Sensing Applications
APC Materials - High Power Applications

 

When subjected to a mechanical force certain crystalline minerals become electrically polarized. Tension and compression generate voltages of opposite polarity, in proportion to the applied force. The converse of this relationship also is true: a voltage-generating crystal exposed to an electric field lengthens or shortens according to the polarity of the field, and in proportion to the strength of the field. These behaviors are the piezoelectric effect and the inverse piezoelectric effect, respectively. Piezoelectric materials have been adapted to an im­pressive diversity of sensing and action applications, including generation of sonic and ultrasonic signals. For many of these applications there are no practical alternatives.

Metal oxide-based piezoelectric ceramics and other man-made materials have enabled designers to employ the piezoelectric effect and the inverse piezoelectric effect in applications for which natural materials are unsuitable. The composition, shape, and dimensions of a piezoelectric ceramic element can be tailored to meet demanding requirements. Further, these materials are physically strong and chemically inert, and they are relatively inexpensive to manufacture.

A ceramic element of suitable composition is made piezoelectric by exposing the element to a strong direct current electric field. When the electric field is removed the element is permanently polarized (poled) and elongated in the direction of the field. Subsequently, compression along the direction of polarization, or tension perpendicular to the direction of polarization, generates voltage of the same polarity as the polarizing voltage. Tension along the direction of polarization, or compression perpendic­ular to the direction of polarization, generates voltage with polarity opposite that of the polarizing voltage. This conversion of mechanical energy into electrical energy—generator action—is used in fuel-igniting de­vices, solid state batteries, and other products.

Please contact an APCI Representative for details.

 

Piezo Sale Need a few parts to test? Need parts quickly?
Check out our Piezo Sale! New parts added weekly.

Physical and Piezoelectric Properties of APC Materials

Download Materials Chart as PDF

APC Material: 840 841 850 854 855 860 880
Navy Type Equivalent Navy I Hybrid Navy II Navy V Navy VI Porous Navy III
Relative Dielectric Constant
KT 1275 1375 1900 2750 3300 1200 1050
Dielectric Dissipation Factor (Dielectric Loss(%)*
tan δ 0.60 0.40 ≤ 2.00 ≤ 2.00 ≤ 2.50 ≤2.00 0.40
Curie Point (°C)**
Tc 325 320 360 250 200 360 310
Electromechanical Coupling Factor
kp 0.59 0.60 0.63 .66 0.68 0.50 0.50
k33 0.72 0.68 0.72 .68 0.76 0.45 0.62
k31 0.35 0.33 0.36 - 0.40 - 0.30
k15 0.70 0.67 0.68 - 0.66 - 0.55
 
d33 290 300 400 600 630 380 215
-d31 125 109 175 260 276 - 95
d15 480 450 590 625 720 - 330
Piezoelectric Voltage Constant (10-3 Vm/N or 10-3 m2/C)
g33 26.5 25.5 24.8 25.5 21.0 38.0 25.0
-g31 11.0 10.5 12.4 - 9.0 - 10.0
g15 38.0 35.0 36.0 - 27.0 - 28.0
Young's Modulus (1010 N/m2)
YE11 8.0 7.6 6.3 6.0 5.9 - 9.0
YE33 6.8 6.3 5.4 5.2 5.1 - 7.2
Frequency Constants (Hz*m or m/s)
NL (longitudinal) 1524 1700 1500 - 1390 - 1725
NT (thickness) 2005 2005 2040 2000 2079 1390 2110
NP (planar) 2130 2055 1980 1972 1920 1900 2120
Density (g/cm3)
ρ 7.6 7.6 7.6 7.6 7.6 6.6 7.6
Mechanical Quality Factor
Qm 500 1400 80 70 65 50 1000
Acoustic Impedance (Mrayl)
Za - - 31.5 - - 16.5 -

 

APC Material: 842 844

851

881 Type I Type II Type III
 
Equivalent APC Material  Type 1  

Type II

Type III Type I Type II Type III
Relative Dielectric Constant
KT 1375 1500

1950

1030 1300 1800 1000
Dielectric Dissipation Factor (Dielectric Loss(%)*
tan δ 0.45 0.40

1.50

0.40 1.0 2.0 1.0
Curie Point (°C)**
Tc 325 320

360

310 320 300 300
Electromechanical Coupling Factor (%)
kp 0.65 0.68

0.71

0.58 0.60 .65 .55

kt

0.48

0.48

0.51

0.46

0.40 .40 .40
Piezoelectric Charge Constant (10-12 C/N or 10-12 m/V)
d33 300 300

400

260 275 375 200
Piezoelectric Voltage Constant (10-3 Vm/N or 10-3 m2/C)
g33 26.3 24.5

24.8

26.7 26 25 26
Young's Modulus (1010 N/m2)
YE11 8.0 7.6

6.3

9.0 8 6 9
YE33 6.8 6.3

5.4

7.2 7 5 7
Frequency Constants (Hz*m or m/s)
NT (thickness) 2050 2050

2040

2050 2050 2000 2100
NP (planar) 2230 2250

2080

2300 2200 2000 2200
Density (g/cm3)
ρ 7.6 7.7

7.6

7.6 7.6 7.6 7.6
Mechanical Quality Factor
Qm 600 1500

80

1000 600 80 1000
Contact APC Today

 

The values listed above pertain to test specimens. They are for reference purposes only and cannot be applied unconditionally to other shapes and dimensions. In practice, piezoelectric materials show varying values depending on their thickness, actual shape, surface finish, shaping process and post-processing.

Note: measurements made 24 hours after polarization.
Maximum voltage:5-7 VAC /mil for 850, 851, 855, Type VI VDC

~2X. 9-11 VAC /mil for 840, 841, 842, 844, 880, 881 VDC ~2X.

*At 1 kHz, low field.
**Maximum operating temperature = Curie point/2.

Standard Electrical Tolerances (Tighter tolerances avaliable on request)

- Capacitance: ±20%
- d33 Value: ±20%
- Frequency: ±5% (to ±0.5% on request)

Background on APC's Piezo Materials

Having a consistent piezoelectric material is important to the development and production of piezo devices. APC’s piezoelectric materials are known in the industry for their purity and low variability in mechanical and electrical properties.

APC’s piezo materials fall into two broad categories: hard piezo material and soft piezo material.

A soft piezo material exhibits: larger piezoelectric constants, higher permittivity, larger dielectric constants, higher dielectric losses, larger electromechanical coupling factors, low mechanical quality factors, a lower coercive field, poor linearity, and is easier to depolarize. This combination of properties makes soft piezo materials ideal for many sensing applications. APC’s primary soft pizeo materials are APC 850, APC 854 and APC 855.

A hard piezo material exhibits: smaller piezoelectric constants, lower permittivity, smaller dielectric constants, lower dielectric losses, smaller electromechanical coupling factors, high mechanical quality factors, a higher coercive field, better linearity, and is harder to depolarize. This combination of properties makes hard piezo materials ideal for many high power applications. APC’s primary hard pizeo materials are APC 840, 841, and APC 880.

APC’s 840, 841, 850, 854, 855, and 880 piezo materials are all proudly manufactured in the United States of America.

APC's piezoelectric ceramics are generally manufactured from PZT (Pb - lead, Zr - zirconium, Ti - titanium). This compound class shows much better piezo-electrical and piezo-mechanical efficiency than naturally occurring piezoelectric materials such as quartz.

The PZT- formulation can be varied with a variety of dopants allowing for a broad spectrum of material properties optimized for different application profiles.

Unfortunately, not all desirable properties can be put into a distinct piezo compound. Piezo-mechanics is to some extent is an "art of compromise", when selecting a suitable material for a distinct application.

Developing new piezo-materials is a steadily ongoing process in the ceramic industry. PZT is the most widely used smart material for solid-state actuation. Alternative materials with enhanced strain capability are under study, but all these "innovative" materials have drawbacks regarding common driving conditions.

PZT ceramics' material data are usually defined at low field excitation where nonlinearities are not dominant. In practice, high electrical fields are applied often applied resulting in a nonlinear enhanced response ("ferro-effects") and altered parameters. Nevertheless, for reasons of comparison with materials from different suppliers, the classical characterizations are used for describing piezoelectric ceramics. The data shown in the tables are valid for room temperature operation.

Piezoelectric ceramics are a ferroelectric compound. This means, that the electro-mechanical conversion process for producing a motion is related a kind of self-enhancement process based on an internal reorganization of the material's structure. This self-enhancement process results in the higher piezo-electrical efficiency of PZT when compared to natural materials like quartz.

Have questions about APC International's piezo products? Contact us or call us at (570)726-6961 to learn more information. 


For more information about APC International’s piezoelectric materials please consult the following:

Materials Overview
Choosing An APC Material
APC Materials for Sensing Applications
APC Materials for High Power Applications

 

APC Materials Physical & Piezoelectric Properties

Coming soon...

Choosing an APC Piezoelectric Material

We manufacture an extensive selection of piezoelectric elements from our specially formulated, highest purity lead zirconate / lead titanate ceramics. Use an APC soft (sensor) ceramic - APC 850 or APC 855 - for low-power resonance or non-resonance devices, when high coupling and/or high charge sensitivity are important. Choose an APC hard (high power) ceramic - APC 840, APC 841, or APC 880 - when high power characteristics are required.

APC 850 is an excellent piezoelectric material for flow or level sensors, such as ultrasonic or Doppler flow meters, gas flow sensors, and ultrasonic level sensors, for ultrasonic NDT / NDE applications, or for accurate inspections of automotive, structural, or aerospace products (construction materials, structural welds, transmission lines, steel storage tanks). APC 850 is also ideal for high performance transducers for medical imaging applications. A high dielectric constant, high coupling, high charge sensitivity, high density with a fine grain structure, a high Curie point, and a clean, noise-free frequency response are characteristic of APC 850.

APC 855 is well suited to applications similar to those in which APC 850 is used, when high permittivity and high piezoelectric charge coefficients are required.

APC 840 and APC 841 materials are widely used for generating ultrasonic or high-voltage energy in ultrasonic power, sonar market, etc. Important characteristics of APC 841 include a high piezoelectric charge constant (d33) relative to reference values for this formulation, greater power output per volume of material, a high mechanical quality factor that reduces mechanical loss and allows a lower operating temperature, and a low dissipation factor that ensures cooler, more economical operation.

High dielectric stability and low mechanical loss under demanding conditions make APC 880 an excellent choice when the highest electrical drive is required.

 

APC Piezoelectric Materials Recommendations for Specific Applications
Application 840
(842)
841
(844)
880
(881)
850
(851)
855
(Type VI)
accelerometers       Checkmark Checkmark
bilaminar actuators       Checkmark Checkmark
cryogenic SEMs     Checkmark    
flow meters       Checkmark Checkmark
gas ignitors, impact-type       Checkmark Checkmark
gas ignitors, squeeze-type Checkmark Checkmark      
high frequency transducers Checkmark Checkmark      
high power actuators Checkmark Checkmark      
high stress pressure sensors Checkmark Checkmark      
hydrophones       Checkmark Checkmark
level sensors       Checkmark Checkmark
medical monitoring /
medical diagnostic
      Checkmark Checkmark
microphones       Checkmark Checkmark
motors, vibratory Checkmark Checkmark      
precise movement control       Checkmark Checkmark
pressure sensors       Checkmark Checkmark
thickness gauges       Checkmark Checkmark
transformers Checkmark Checkmark      
ultrasonic atomizers Checkmark Checkmark      
ultrasonic cleaners Checkmark Checkmark      
ultrasonic micro-bonding Checkmark Checkmark      
ultrasonic mixing / dispersion     Checkmark    
ultrasonic surgery     Checkmark    
ultrasonic welding     Checkmark    
underwater echo sounders Checkmark Checkmark      
For more information about APC International’s piezoelectric materials please consult the following:
Material Overview
Physical & Piezoelectric Material Properties
APC Materials - Sensing Applications
APC Materials - High Power Applications

Contact APC International today to discuss your piezoelectric ceramic or piezo device requirements.

Contact Us Today